Heat capacity


Heat capacity or thermal capacity CC is the amount of heat QQ that needs to be absorbed by a body to incur a unit change in temperature TT, such that

C=limT0ΔQΔT=UT=TSTC=\lim_{ T \to 0 } \frac{\Delta Q}{\Delta T}=\frac{ \partial U }{ \partial T } =T \frac{ \partial S }{ \partial T }

where UU is the internal energy and SS is entropy. It is an extensive property, with more massive objects having more heat capacity, though it the quantity varies greatly depending on the thermodynamic state of the body and is better represented as the function C(P,T)C(P,T), with PP pressure and TT temperature. The entropy-dependent formula is a convenient way to measure entropy differences experimentally, as we can see by inverting the formula:

ΔS=T1T2C(T)TdT\Delta S=\int_{T_{1}}^{T_{2}} \frac{C(T)}{T}dT

With an experimental fit of C(T)C(T), we can perform consistency tests on the theory.

The heat capacity also depends on the kind of thermodynamic transformation that's applied onto the body. Different types of transformations are usually denoted with a subscript: CVC_{V} for constant volume ones, CPC_{P} for isobaric ones, etc.