Fermi-Dirac distribution


The Fermi-Dirac distribution is a Probability distribution that describes the behavior of a system of NN non-interacting fermions in thermal equilibrium. Its Probability density function is

ni=1eβ(εiμ)+1=1z1eβεi+1\langle n_{i} \rangle =\frac{1}{e^{\beta(\varepsilon_{i}-\mu)}+1}=\frac{1}{z^{-1}e^{\beta \varepsilon_{i}}+1}

ni\langle n_{i} \rangle is the average number of fermions in the ii-th single-particle state of energy εi\varepsilon_{i}, μ\mu is the system's chemical potential, β=1/kBT\beta=1/k_{B}T is the inverse temperature, with kBk_{B} the Boltzmann constant and TT the temperature, and zz is the fugacity. The normalization constant is

ini=N\sum_{i}n_{i}=N

Since we are working with fermions, the Pauli exclusion principle must hold, which is to say that ni<1\langle n_{i} \rangle< 1. In fact, at low temperatures, this causes the distribution to approach the Heaviside step function according to the limit

limT0ni=Θ(μεi)\lim_{ T \to 0 } \langle n_{i} \rangle=\Theta(\mu-\varepsilon_{i})

From David Tong's lecture notes on statistical physics. EFE_{F} is the Fermi energy.